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Anonymous
Posted on Wednesday, September 22, 2004 - 8:01 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

Instead of using the nickel platinum wire to make the electrodes, can I use electronic solder coils?
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Andrew
Posted on Wednesday, September 22, 2004 - 9:48 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

Unless they are platinum, no. Platinum is needed as a catalyst. Without it you would get electrolysis, but the gasses wouldn't recombine.
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Anonymous
Posted on Sunday, November 28, 2004 - 11:14 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

Is silver a catalyst?
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Simon Quellen Field (Sfield)
Posted on Monday, November 29, 2004 - 10:08 am:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

Silver is a catalyst for some reactions, such as decomposing
hydrogen peroxide to produce water and oxygen. However, it will
not work in the fuel cell to convert hydrogen and oxygen into
water and electricity.
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deepayan kumar
Unregistered guest
Posted From: 221.134.168.216
Posted on Saturday, August 20, 2005 - 11:42 am:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

as platinum is very expensive as a catalyst,so is there any alternative to it which can act as a catalyst?
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Simon Quellen Field (Sfield)
Senior Member
Username: Sfield

Post Number: 646
Registered: 12-2004
Posted on Saturday, August 20, 2005 - 2:54 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

Palladium, Rhodium, Iridium...
Platinum is best.

If there was a cheap replacement, we wouldn't be using platinum.
Nickel and stainless steel are mildly catalytic, but none of the
people who have written me after trying it have had any success.

We use the platinum fuel cell because it is easy for kids to get
it to work. Commercial cells use more complicated technology such
as proton exchange membranes.
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Arthur Yip (Peregrineay)
Junior Member
Username: Peregrineay

Post Number: 9
Registered: 4-2005
Posted on Friday, September 30, 2005 - 9:23 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

Proton-exchange-membranes also use platinum, but in microscopic levels for more surface area.

There have been research at universities on high temperature fuel cells. With the high temperature and pressure involved, nickel-tin alloys were found to work as electrodes too.
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Josh (Unregistered Guest)
Unregistered guest
Posted From: 72.235.129.42
Posted on Thursday, December 22, 2005 - 12:58 am:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

So can Hydrogen Peroxide be split with a DC 12 volt 1000 MA transformer and
the most pure silver you can find ?
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Simon Quellen Field (Sfield)
Senior Member
Username: Sfield

Post Number: 838
Registered: 12-2004
Posted on Friday, December 23, 2005 - 7:31 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

You don't need silver, pure or otherwise.
Hydrogen Peroxide will electrolyse much like water will.
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Arthur Yip (Peregrineay)
Member
Username: Peregrineay

Post Number: 19
Registered: 4-2005
Posted on Sunday, February 5, 2006 - 6:55 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

However, Josh, H2O2 will not produce hydrogen and oxygen at each end. The products of electrolysing hydrogen peroxide are water and oxygen. Why are you splitting hydrogen peroxide? Hydrogen gas can be safely released into the environment because it dissipates quickly.

(Message edited by peregrineay on February 5, 2006)
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Simon Quellen Field (Sfield)
Senior Member
Username: Sfield

Post Number: 997
Registered: 12-2004
Posted on Sunday, February 5, 2006 - 11:53 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

Actually, silver is a good catalyst to dissociate H2O2, without
any need for electricity. The reaction can be vigorous enough to produce
steam along with the oxygen.

Arthur -- are you sure about the decomposition products under electrolysis,
or is that an assumption? Even if you started with pure H2O2,
after it released oxygen you would have water with current running through
it. Are you certain there is no H2 produced? Maybe we should try
the experiment.
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Arthur Yip (Peregrineay)
Member
Username: Peregrineay

Post Number: 20
Registered: 4-2005
Posted on Sunday, February 5, 2006 - 11:59 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

I guess not, total products would be hydrogen and oxygen because you've got hydrolysis happening with the H2O2 solution. Thanks for clearing that up! But I still wonder: why split hydrogen peroxide? I guess Josh wants equal production of hydrogen and oxygen?

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