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anonymous
Posted on Sunday, April 4, 2004 - 5:06 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

For a chemistry demonstration, I want to do the reaction of powdered aluminum and ground iodine. I can make the similar reaction work with zinc (powdered zinc + ground iodine, a couple drops of water as a catalyst. Purple cloud of sublimed iodine results), but I can't make the aluminum work. I can't figure out why the zinc would work and the aluminum would not: aluminum is more reactive. I've been doing the two experiments exactly the same (changing only the type of metal). The aluminum reaction is supposed to be stronger than the zinc one, even producing a flame.

Any hints?
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Simon Quellen Field (Sfield)
Posted on Sunday, April 4, 2004 - 6:02 pm:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

Aluminum is protected by a thin coating of aluminum oxide.
With zinc, the bare metal can touch the water and iodine.
You may need something to overcome the protective oxide
barrier -- perhaps some impurities in the water or some
potassium iodide in the iodine powder. Try a slightly
acidic water and see what happens.

Ask the people who describe the reaction on their web sites:
"http://jchemed.chem.wisc.edu/JCESoft/CCA/CCA1/R1MAIN/CD1R1260.HTM"
"http://chemmovies.unl.edu/chemistry/redoxlp/a10.html"
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I. Dimov (Overrider)
Junior Member
Username: Overrider

Post Number: 6
Registered: 12-2005
Posted on Saturday, December 31, 2005 - 6:45 am:   Edit PostDelete PostView Post/Check IPPrint Post   Move Post (Moderator/Admin Only)Ban Poster IP (Moderator/Admin only)

my chem teacher heats the stuff up, to put in extra E.

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